By Gregoire Nicolis, Dominique Maes, Stuart A. Rice, Aaron R. Dinner
The Advances in Chemical Physics series—the innovative of study in chemical physics
The Advances in Chemical Physics sequence offers the chemical physics and actual chemistry fields with a discussion board for severe, authoritative reviews of advances in each region of the self-discipline. jam-packed with state of the art examine said in a cohesive demeanour no longer came upon in other places within the literature, each one quantity of the Advances in Chemical Physics sequence offers contributions from the world over popular chemists and serves because the ideal complement to any complex graduate classification dedicated to the examine of chemical physics.
This quantity explores:
Kinetics and thermodynamics of fluctuation-induced transitions in multistable platforms (G. Nicolis and C. Nicolis)
Dynamical infrequent occasion simulation strategies for equilibrium and nonequilibrium structures (Titus S. van Erp)
Confocal depolarized dynamic gentle scattering (M. Potenza, T. Sanvito, V. Degiorgio, and M. Giglio)
The two-step mechanism and the solution-crystal spinodal for nucleation of crystals in answer (Peter G. Vekilov)
Experimental experiences of two-step nucleation in the course of two-dimensional crystallization of colloidal debris with short-range appeal (John R. Savage, Liquan Pei, and Anthony D. Dinsmore)
On the function of metastable intermediate states within the homogeneous nucleation of solids from resolution (James F. Lutsko)
Effects of protein dimension at the high-concentration/low-concentration section transition (Patrick Grosfils)
Geometric constraints within the self-assembly of mineral dendrites and platelets (John J. Kozak)
What can mesoscopic point in situ observations train us approximately kinetics and thermodynamics of protein crystallization? (Mike Sleutel, Dominique Maes, and Alexander Van Driessche)
The skill of silica to urge biomimetic crystallization of calcium carbonate (Matthias Kellermeier, Emilio Melero-GarcÍa, Werner Kunz, and Juan Manuel GarcÍa-Ruiz)
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Extra resources for Advances in Chemical Physics, Kinetics and Thermodynamics of Multistep Nucleation and Self-Assembly in Nanoscale Materials
More than one century ago, Wilhelm Ostwald proposed a step rule to explain certain observations on the formation of crystalline materials from the melt . According to this rule, typically it is not the most stable form of the material but the least stable one that crystallizes ﬁrst. The status of this rule in the light of present day knowledge on nucleation has been discussed recently in the literature [34, 35]. , high concentration of a key substance) for the appearance and growth of nuclei possessing the structure of the ﬁnal phase.
K. Tomita, T. Ohta, and H. Tomita, Prog. Theor. , 52, 1744 (1974). 5. R. Kubo, K. Matsuo, and K. Kitahara, J. Stat. , 9, 51 (1973). 6. H. Gang, Phys. Rev. A, 36, 5782 (1987). 7. L. Bertini, A. D. Sole, D. Gabrielli, G. Jona-Lasinio, and C. Landim, Phys. Rev. , 87, 040601 (2001). 8. P. Glansdorff and I. Prigogine, Thermodynamic Theory of Structure, Stability and Fluctuations, Wiley, London, 1971. 9. S. De Groot and P. Mazur, Nonequilibrium Thermodynamics, North Holland, Amsterdam, 1962. 10. G. Nicolis and C.
High concentration of a key substance) for the appearance and growth of nuclei possessing the structure of the ﬁnal phase. The analysis also shows that this is only one out of several scenarios and provides information on its realizability depending on the values of the parameters present in the problem. Transitions between states are a generic phenomenon observed in a multitude of systems of interest in physical, life, engineering, and environmental sciences . It constitutes one of the principal signatures of the dynamics of complex systems as it endows them with the ability to evolve, to choose, and to adapt and extends in this respect beyond the examples of protein or colloid crystallization and similar phase transition phenomena.
Advances in Chemical Physics, Kinetics and Thermodynamics of Multistep Nucleation and Self-Assembly in Nanoscale Materials by Gregoire Nicolis, Dominique Maes, Stuart A. Rice, Aaron R. Dinner